Polyquaternium-11 is a cationic, water-soluble copolymer (quaternized vinylpyrrolidone–dimethylaminoethyl methacrylate) valued for its strong substantivity to keratinous substrates and its ability to form clear, flexible, non-tacky films. In skincare, these films improve slip, laydown, and after-feel, helping reduce tack in humectant-rich systems and enhancing perceived smoothness without heavy occlusion. Because the polymer remains largely on the stratum corneum surface, it is used as a skin-conditioning and sensory aid in lightweight body lotions, toners, and color cosmetics where a uniform film improves rub-in and reduces pilling.
In hair-care, Polyquaternium-11 is a workhorse conditioning/antistatic and styling polymer. Its positive charges electrostatically anchor to the negatively charged hair surface (especially on chemically or physically damaged fibers), decreasing inter-fiber friction, improving wet and dry combability, and delivering styling hold with frizz control through uniform film formation. The polymer is compatible with anionic, nonionic, and amphoteric surfactants, enabling robust deposition from shampoos as well as strong performance in mousses, gels, and sprays. These structure–performance links are well documented for cationic conditioning polymers and are directly reflected in PQ-11 technical literature and INCI references.

Quick Insights
Ingredient Rating:
GOOD
Type of Ingredient:
Texture Enhancer, Conditioner and Anti-Frizz Agent
Intended Function:
Cationic film-former that enhances combability, controls flyaways/frizz, and improves sensory feel in water-based systems.
Common Applications:
Conditioning shampoos, rinse-off conditioners, leave-in conditioners, hair gels/mousses/sprays; lighter skin and color-cosmetic systems for smoother application.
Target Audience:
Brands formulating performance hair-care (damage/frizz control, hold/definition) and sensorially refined leave-on skincare seeking clear, non-tacky films.
Also Known As:
CAS 53633-54-8.
Safety Analysis
Regulatory & safety consensus. Polyquaternium-11 appears in authoritative cosmetic ingredient databases as a hair-conditioning/film-forming polymer permitted in both leave-on and rinse-off products. Industry safety summaries report a low incidence of irritation/sensitization at typical cosmetic concentrations, consistent with its macromolecular size and primarily surface-level action. The Cosmetic Ingredient Review and PCPC’s Cosmetics Info note the extensive history of safe use and typical functional roles (conditioning, antistatic, fixative).
Formulation and exposure considerations. Being cationic and high-molecular-weight, PQ-11 is not expected to penetrate viable skin to an appreciable extent; it deposits onto hair/skin and is removed with cleansing.
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