Malic Acid, an alpha‑hydroxy acid (AHA) naturally derived from fruits like apples and pears, offers effective yet gentle exfoliation by loosening cohesion between epidermal corneocytes, thus fostering smoother skin texture and a more radiant complexion. Its larger molecular size compared to glycolic or lactic acid reduces skin penetration, making it particularly well‑suited for sensitive or reactive skin types. Additionally, it exhibits humectant properties, attracting and retaining moisture within the skin, helps balance skin pH, and supports collagen renewal and anti‑aging outcomes by promoting cell turnover.
Although the majority of research focuses on skin applications, haircare use is more limited. When used in formulations such as hair sprays or shampoos, Malic Acid functions primarily as a pH adjuster or mild exfoliant for the scalp, but formulations must minimize ocular exposure due to irritation risk.

Quick Insights
Ingredient Rating:
GOOD
Type of Ingredient:
Exfoliant, Soother, Anti-Aging Agent and Chelating Agent
Intended Function:
Gently exfoliate dead skin cells, boost hydration, balance pH, and assist in skin renewal and firmness.
Common Applications:
Used in facial cleansers, toners, serums, exfoliating masks, moisturizers, and gentle scalp formulations to improve texture, radiance, hydration, and regulate pH.
Target Audience:
Formulators targeting sensitive, aging, dry, or acne‑prone skin looking for gentle resurfacing with hydration and minimum irritation. Also suitable for manufacturers of mild scalp or leave‑on hair products where pH balance is critical.
Also Known As:
2‑Hydroxybutanedioic acid, Hydroxybutanedioic acid, D‑Malic acid, L‑Malic acid.
Safety Analysis
Malic Acid can cause skin and ocular irritation, especially in high concentrations or low pH formulations. In animal and human patch tests, moderate-to-strong irritation was observed on skin, and strong ocular irritation occurred with high‑concentration exposures. The Cosmetic Ingredient Review (CIR) Panel determined that Malic Acid and its salts are safe for cosmetic use at typical concentrations, especially as a pH adjuster. Human repeat insult patch tests (HRIPT) revealed no sensitization at 1%, and no sensitization data exist up to a maximum of 2.1% leave‑on concentration.

References
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